Indexes allow the database application to find data fast, without reading the whole table.The CREATE INDEX statement is used to create indexes in tables.
CREATE INDEX Syntax
CREATE INDEX index_name ON table_name (column_name)
CREATE UNIQUE INDEX Syntax
CREATE UNIQUE INDEX index_name ON table_name (column_name)
Example :
Create an index named username_index for the field username:
CREATE INDEX username_index ON users (username) USING BTREE;
If you want to create an index on a combination of columns, you can list the column names within the parentheses, separated by commas as shown below
CREATE INDEX user_index ON users (username,email) USING BTREE;
you can find more about index at : http://dev.mysql.com/doc/refman/5.0/en/create-index.html